Determination of bisphenol A (BPA) in water by gas chromatography-mass spectrometry.
EUROANAL : Euroanalysis IX. Bologna, 1996/09/01.
Copyright (c) 1997 Elsevier Science B.V. All rights reserved.
A simple method for determination of bisphenol A in waters was developed using Gas Chromatography-Mass Spectrometry with a Selected Ion Monitoring (GC/MS-SIM).
A 1000ml water sample was extracted with dichloromethane in acid medium.
No clean-up was necessary.
Anthracene-d10 was used as an internal standard.
The applicable concentration range was 2.5 to 10ngml-1 in water samples.
The detection limit was 0.6ngml-1.
The method was applied satisfactorily to the determination of oestrogenic environmental pollutants in sea water from M & aacute ; laga (Spain) and spring water from the fertile plain of Granada (Spain).
The method was validated using the standard addition methodology.
The accuracy of the proposed method was verified by applying a Student t test.
The relative standard deviations established for the linear concentration range was between 8.6 and 1.5%.
Mots-clés Pascal : Analyse trace, Chromatographie phase gazeuse, Spectrométrie masse, Méthode couplée, Enrichissement chimique, Extraction liquide liquide, Pollution, Endocrinopathie, Phénols, Composé aromatique, Eau, Eau surface, Eau mer, 4,4p-Méthylènediphénol(alpha,alpha-diméthyl)
Mots-clés Pascal anglais : Trace analysis, Gas chromatography, Mass spectrometry, Coupled method, Chemical enrichment, Liquid liquid extraction, Pollution, Endocrinopathy, Phenols, Aromatic compound, Water, Surface water, Seawater
Notice produite par :
Inist-CNRS - Institut de l'Information Scientifique et Technique
Cote : 97-0363406
Code Inist : 001D16A04A. Création : 12/09/1997.